PACE (Plasma-Assisted Co-Evaporation) Processing
Copper-indium-gallium-selenide (CIGS) films are wide bandgap semiconductors that are employed as absorbers in photovoltaic devices. By partially replacing selenium with sulfur (CIGSS) one may engineer the bandgap of this material in order to optimize photovoltaic performance. Selenization/sulfurization of metallic precursor films is typically done thermally using elemental S2/Se2 vapors or gases like H2S/H2Se. We are developing novel plasma-assisted co-evaporation (PACE) processing techniques for this step. Anticipated advantages include temperature reduction, improved material utilization, and better control of the S/Se ratio.
This industrial/academic collaboration is managed by Dr. Ingrid Reppins of ITN Energy Systems. The student team includes PhD candidate Sreenivas Kosaraju, MS candidate Gunnar Recht, and undergraduate researcher John Harvey.
This project is supported by the National Renewable Energy Laboratory (NREL) through a subcontract with ITN Energy Systems.